Sunday, February 21, 2016

History of Chemistry

Classification by nuclear tilt . From the time of Dalton to 1860 in the pill pusherry was non accurate description of atomic tilt. The administ dimensionn is found on equivalent freight , proposed by the face druggist William Wollaston (1766 - 1828) , was found on the ratio in which the elements move be feature , and every pill roller could make a list of atomic burdens. There was no starting portend for the creation of elements and no agreement on how to express the coordinate of compounds. In 1860 the basic International chemic Congress in Karlsruhe ( Ger many an(prenominal) a(prenominal)) Italian druggist Stanislao Cannizzaro (1826 - 1910 ) once once again brought back to vivificationtime forgotten the hypothesis of their fellow Amedeo Avogadro (1776 - 1856 ), who , based on the commiting move Lussac law volume relations predicted that touch volumes of gases learn the resembling offspring of molecules. Cannizzaro argued that victimization Avogadro s hypothesis so-and-so distinguish amid atomic weightiness and molecular weight Gaseous elements and puzzle out clarity to the retire of atomic weight in general.\nIn 1869 the great Russian pill pusher Dmitri Ivanovich Mendeleev , who was pose at the social intercourse in Karlsruhe, promulgated his midweekly parry . All cognise elements arranged it fit in to their increasing atomic weight and stony-broke into periods and themes that correspond to the swop of valence. The table had been leftfield wide open space for another(prenominal) undiscovered elements, some(prenominal) of them even appropriated the label Mendeleev ( kabor , kaalyuminiy and kakremniy ; prefix ka content the same ). The slight accuracy of the periodic law demonstrate discovery of tabun in 1875 , like in their properties kaalyuminiyu , scandium ( kabora ) in 1879 and Germany ( kakremniya ) in 1886. Organic himiya.Protyahom mediocre 18. the question of the alliance between organisms a nd chemic substances scientists guided the philosophy of vitalism the doctrine that was considering life as a superfluous phenomenon that obeys no laws of the universe, and the influence of special vitality. This view was transmittable by many scientists and 19. , Though its foundations were shake back in 1777, when Lavoisier suggested that respiration dish similar to burning. The frontmost experimental pidtvrdzhennya star of in perfect and original world were veritable in the primal 19th century.\nIn 1828 the German chemist Friedrich Wöhler (1800 - 1882) by heating ammonium ion cyanate (this connection unconditionally pryrahovuvalosya to in original substances) , was water supply waste crossroad of humans and animals. In 1845 Adolf Kolbe (1818 1884) , a backer of Wohler , synthesized acetic superman from the initial elements carbon, heat content and oxygen. In 1850 -ies the French chemist capital of South Dakota Berthelot (1827 -1907 ) began systematic add o n the entailment of organic compounds and obtained methyl group and ethyl alcohols , methane, benzene, acetylene. A systematic airfield of natural organic compounds showed that they all contain one or more atoms of carbohydrates and a lot of them heat content atoms . As a result of these studies , the German chemist Friedrich elevated Kekulé (1829 - 1896) in 1867 defined organic chemical science as the chemistry of carbohydrate compounds . A new come along to the analysis of organic synthesis was a German chemist Justus von Liebig (1803 - 1873) the founder of the notable research and educational laboratories in Hisenskomu University. In 1837 Liebig with the French chemist Jean Baptiste Dumas (1800 - 1884) verbalise the idea of ​​a stem as a particularised unchanging group of atoms that is part of many organic compounds (eg radical CH3). It became clear that influence the structure of macroscopic molecules is possible unaccompanied by scope the struct ure of a certain number of radicals.

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